Towards Self-Organized Anodization of Aluminum in Malic Acid Solutions—New Aspects of Anodization in the Organic Acid

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1. Aluminum anodization

The history of electrochemical oxidation of aluminum dates back to the beginning of the last century. Anodic treatment of aluminum were intensively investigated to obtain protective and decorative films on its surface [1]. More recently, applications of porous alumina with a huge surface area and a relatively narrow pore size distribution have been exploited [2]. For example, several attempts t...

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Self-ordered anodic aluminum oxide formed by H2SO4 hard anodization.

The self-ordering of nanoporous anodic aluminum oxide (AAO) in the course of the hard anodization (HA) of aluminum in sulfuric acid (H2SO4) solutions at anodization voltages ranging from 27 to 80 V was investigated. Direct H2SO4-HA yielded AAOs with hexagonal pore arrays having interpore distances D(int) ranging from 72 to 145 nm. However, the AAOs were mechanically unstable and cracks formed a...

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Self-organized porous anodic alumina (PAA) formed by electrochemical anodization have become a fundamental tool to develop various functional nanomaterials. However, it is still a great challenge to break the interpore distance (Dint) limit (500 nm) by using current anodization technologies of mild anodization (MA) and hard anodization (HA). Here, we reported a new anodization mode named "Janus...

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ژورنال

عنوان ژورنال: Materials

سال: 2020

ISSN: 1996-1944

DOI: 10.3390/ma13173899